府 is built from the 广 (house on a cliff) and 付 components.
It reads フ like 付, as do 腐 and 符 — learn 付 once and the family's reading comes with it.
A common word using 府 is 政府 (せいふ), meaning “government, administration”.
Kanji that look similar include 底, 店, 床, and 序.